A.Calculate ΔS°(universe) for the decomposition of 1 mol of gaseous phosphine (PH3) to form white phosphorus and gaseous
S° (J/K · mol .) . ΔfH° (kJ/mol)
O2(g) | 205.07 | 0 |
H2(g) | 130.7 | 0 |
H2O(ℓ) | 69.95 | -285.83 |
P4(s, white) | 41.1 | 0 |
PH3(g)210.24 5.47
N2(g)191.56 0
NH3(g)192.77 -45.90
Cl2(g)223.08 0
HCl(g)186.2 -92.31
CO2(g)213.74 -393.509
C(s, graphite)0 5.6
ΔS°(universe) = J/K
B.Determine whether the decomposition of gaseous phosphine (PH3) to form white phosphorus and gaseous hydrogen is spontaneous at 25 °C.
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