Question

When trans-stillbene and cis-stillbene react with pyridinium hydrobromide perbromide (PHP), one of them is getting a...

When trans-stillbene and cis-stillbene react with pyridinium hydrobromide perbromide (PHP), one of them is getting a racemic product. Which starting material leads to the racemic product?

Homework Answers

Answer #1
  1. The cis and trans isomers of stiblene has different geometries, when they are reacted with pyridinium tribromide, they give stereoisomers bromonium ion and eventually their products different in the stereochemistry.
  2. The product formed is 1,2-dibromo-1,2-diphenylethane has two sterogenic centres, which results in four stereoisomers.
  3. Trans-stiblene forms two meso products...image I
  4. cis-stiblene forms a reacmic mixture (equal amounts of two non-superimpossible mirror images isomers).....image -II
  5. See the attached image

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Explain which of the two 1-bromo-3-tertbutylcyclohexane isomers, cis or trans, would be expected to react fastest...
Explain which of the two 1-bromo-3-tertbutylcyclohexane isomers, cis or trans, would be expected to react fastest in an elimnation reaction to produce the cyclohexene products.
Synthesize trans-2-butene(target product) from cis-2-butene (starting material). Step 1 Reagents that I need is         ...
Synthesize trans-2-butene(target product) from cis-2-butene (starting material). Step 1 Reagents that I need is                            [ Select ]                       ["Br2 in Chlorform", "HBr in dichloromethane", "HBr with MeOOMe and light", "NBS"]       Step 2 Reagents that I need is                            [ Select ]                       ["NaNH2 in liquid ammonia", "Aqeous NaOH", "KOt-Bu in t-BuOH",...
when ionic bromination of cyclohexene is carried out, the product is trans-1,2-dibromocyclohexane. gas chromatogarphic analysis with...
when ionic bromination of cyclohexene is carried out, the product is trans-1,2-dibromocyclohexane. gas chromatogarphic analysis with a heated injection port can result in the elimination of Br2 from the dibromo product to regenerate the starting alkene. Thus, the GC properties of both the starting material and the adduct are of interest. Predict the relative retention times of cyclohexene and trans-1,2-dibromocyclohexane on a nonpolar interst.
Which covalent bond is the most polar, and which is the least polar? C-N               C-O               &nbsp
Which covalent bond is the most polar, and which is the least polar? C-N               C-O                     C-F Including all constitutional isomers and stereoisomers, there are six different compounds with the formula C4H8.    Provide IUPAC names (including cis/trans or E/Z, as needed) for five of them. Starting with propylbenzene, synthesize meta-bromobenzoic acid. You may use any other organic or inorganic reagents that you wish.    More than one step will be required -- be sure to list the steps (including reagents and catalysts)...
1)Assume that when adults with smartphones are randomly​ selected, 48​% use them in meetings or clas2)ses....
1)Assume that when adults with smartphones are randomly​ selected, 48​% use them in meetings or clas2)ses. If 6 adult smartphone users are randomly​ selected, find the probability that at least 3 of them use their smartphones in meetings or classes. The probability is 2)   Determine whether or not the procedure described below results in a binomial distribution. If it is not​ binomial, identify at least one requirement that is not satisfied. FourFour hundred different voters in a region with two...
The rise in the value of one currency in relation to another is : Depreciation of...
The rise in the value of one currency in relation to another is : Depreciation of the currency. An appreciation of the currency. A debasement of the currency. A weakening of the currency. Cyclical unemployment refers to unemployment which occurs Because of the seasonal nature of some industries. As a result of the long term decline of the industry. At particular times of the year. As a result of a temporary drop in aggregate demand resulting in a recession. Which...
A firm considering foreign expansion must first decide which markets to enter, when to enter them,...
A firm considering foreign expansion must first decide which markets to enter, when to enter them, and on what scale. Then the firm must decide on the entry mode. The firm's strategy, product, and competition all play parts in making that decision. When a firm's competitive advantage is based on technological competence, a wholly owned subsidiary will often be the preferred entry mode because it reduces the risk of losing control over that competence. A wholly owned subsidiary is also...
When a scientist conducted a genetics experiments with​ peas, one sample of offspring consisted of 953...
When a scientist conducted a genetics experiments with​ peas, one sample of offspring consisted of 953 ​peas, with 723 of them having red flowers. If we​ assume, as the scientist​ did, that under these​ circumstances, there is a 3 divided by 4 probability that a pea will have a red​ flower, we would expect that 714.75 ​(or about 715​) of the peas would have red​ flowers, so the result of 723 peas with red flowers is more than expected. a....
The Business Case for Agility “The battle is not always to the strongest, nor the race...
The Business Case for Agility “The battle is not always to the strongest, nor the race to the swiftest, but that’s the way to bet ’em!”  —C. Morgan Cofer In This Chapter This chapter discusses the business case for Agility, presenting six benefits for teams and the enterprise. It also describes a financial model that shows why incremental development works. Takeaways Agility is not just about the team. There are product-management, project-management, and technical issues beyond the team’s control. Lean-Agile provides...
Logistics industry is one of the leading industries that uses the Information Technologies extensively. By using...
Logistics industry is one of the leading industries that uses the Information Technologies extensively. By using the latest technology gives the companies and the countries competitiveness. _____1____ are the software systems that meet the planning or operational needs of each of the companies in the supply chain and can work integrated with other related systems within and outside the company. The system contains three parts: Order Management System, Warehouse Management System, and Transportation Management System. ____2____ is the interface of...