Elemental sulfur can be recovered from gaseous hydrogen sulfide through the reaction: 2 H2S (g) + SO2 (g) ® 3 S (s) + 2 H2O (l) What volume of H2S (in L, at 0.00°C and one atm) is required to produce 2.00 kg of sulfur by this process?
Molar mass of S = 32.07 g/mol
mass of S = 2.00 Kg = 2000 g
mol of S = (mass)/(molar mass)
= 2000/32.07
= 62.3636 mol
From balanced chemical reaction, we see that
when 3 mol of S reacts, 2 mol of H2S is required
mol of H2S required = (2/3)* moles of S
= (2/3)*62.3636
= 41.58 mol
we have:
P = 1.0 atm
n = 41.58 mol
T = 0.0 oC
= (0.0+273) K
= 273 K
we have below equation to be used:
P * V = n*R*T
1 atm * V = 41.58 mol* 0.0821 atm.L/mol.K * 273 K
V = 932 L
Answer: 932 L
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