Solution :-
lets first calculate the moles of the Cl- in each solutiuon
moles * molarity * volume in liter
moles of NH4Cl = 0.2450 mol per L * 0.025 L = 0.006125 mol NH4Cl = Cl-
moles of FeCl3 = 0.1655 mol per L * 0.0555 L = 0.00919 mol FeCl3
therefore
0.00919 mol FeCl3* 3 mol Cl- / 1 mol FeCl3 = 0.02757 mol Cl-
therefore total moles of Cl- = 0.006125 mol + 0.02757 mol = 0.0337 mol Cl-
total volume = 25.0 ml + 55.5 ml = 80.5 ml = 0.0805 L
now lets calculate the molarity of the Cl^-
[Cl^- ] = moles / volume in liter
= 0.0337 mol / 0.0805 L
= 0.419 M
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