Enter electrons as e-. |
A voltaic cell is constructed in which the anode
is a Sn|Sn2+ half cell
and the cathode is a
I-|I2 half
cell. The half-cell compartments are connected by a salt
bridge.
(Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank.)
The anode reaction is:
__(aq)(s)(l)(g) | + | __(aq)(s)(l)(g) | -----> | __(aq)(s)(l)(g) | + | __(aq)(s)(l)(g) |
The cathode reaction is:
__(aq)(s)(l)(g) | + | __(aq)(s)(l)(g) | -----> | __(aq)(s)(l)(g) | + | __(aq)(s)(l)(g) |
The net cell reaction is:
__(aq)(s)(l)(g) | + | __(aq)(s)(l)(g) | -----> | __(aq)(s)(l)(g) | + | __(aq)(s)(l)(g) |
In the external circuit, electrons migrate _____fromto the
I-|I2 electrode _____fromto
the Sn|Sn2+ electrode.
In the salt bridge, anions migrate _____fromto the
Sn|Sn2+ compartment _____fromto the
I-|I2 compartment.
anode reaction --> must be loss of electrons, from the list shown, I is that species, will donate e-
Sn(s) ---> Sn2+(aq) + 2e-
cathode --> accepts electrons, it will get reduced
2I-(aq) + 2e- --> I2(s)
net ionic:
Sn(s) ---> Sn2+(aq) + 2e-
2I-(aq) + 2e- --> I2(s)
--------------------------------
Sn(s) + 2I-(aq) + 2e- --> I2(s) + Sn2+(aq) + 2e-
d)
electrons migrate from I- towards Sn2+
e)
salt bridge msut counter balance charge via ions so
Sn2+ is decerasing, cations must go to anod
I- is decreasing as well, anions must go to the cathode
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