The standard heat of formation, ΔH∘f, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have ΔH∘f=0. Heat of formation values can be used to calculate the enthalpy change of any reaction.
Consider, for example, the reaction
2NO(g)+O2(g)⇌2NO2(g)
with heat of formation values given by the following table:
Substance | ΔH∘f (kJ/mol) |
NO(g) | 90.2 |
O2(g) | 0 |
NO2(g) | 33.2 |
Then the heat of formation for the overall reaction is
ΔH∘rxn===ΔH∘f(products)2(33.2)−114 kJ/mol−−ΔH∘f(reactants)[2(90.2)+0]
For which of the following reactions is ΔH∘rxn equal to ΔH∘f of the product(s)?
You do not need to look up any values to answer this question.
Check all that apply.
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Check all that apply.
Li(s)+12Cl2(l)→LiCl(s) |
Li(s)+12Cl2(g)→LiCl(s) |
SO3(g)→12O2(g)+SO2(g) |
SO(g)+12O2(g)→SO2(g) |
2Li(s)+Cl2(g)→2LiCl(s) |
S(s)+O2(g)→SO2(g) |
The combustion of propane, C3H8, occurs via the reaction
C3H8(g)+5O2(g)→3CO2(g)+4H2O(g)
with heat of formation values given by the following table:
Substance | ΔH∘f (kJ/mol) |
C3H8 (g) | -104.7 |
CO2(g) | −393.5 |
H2O(g) | −241.8 |
Calculate the enthalpy for the combustion of propane.
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