The given reaction is--
2NH3 ------> N2(g) + 3H2(g)
Here we can see that there is 1 mol of N2 and 3 mol of H2present.
Total number of moles = 1 + 3 = 4
Given, Ptotal = 759 mm Hg
Now, mole of N2 present / total number of moles = partial pressure of N2 / Ptotal
=> 1 / 4 = partial pressure of N2 / 759 mm Hg
=> partial pressure of N2 = 759 mm Hg / 4
=> partial pressure of N2 = 189.75 mm Hg = 189.75 mm Hg * ( 1atm /760 mm Hg) =0.249 atm
Again,
mole of H2 present / total number of moles = partial pressure of H2 / Ptotal
=> 3/ 4 = partial pressure of H2 / 759 mm Hg
=> partial pressure of H2 =( 759 mm Hg x 3) / 4
=> partial pressure of H2 = (2277 / 4) mm Hg
=> partial pressure of H2 = 569.25 mm Hg = 569.25 mm Hg *(1 atm /760 mm Hg) =0.749 atm
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