Question

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1. This week’s oxidation reaction is considered a “Green Chemistry” reaction because of its use of Ozone as the oxidizing agent. In the late 1990s, two chemists, Paul Anastas, and John Warner, co-authored a book regarding how to perform chemical transformations with non-hazardous materials. They created a list of 12 Green Chemistry Principles. Using a textbook or internet, list the 12 principles of Green Chemistry.

2. From your knowledge about oxidation of alcohols, provide a synthetic method for the oxidation of Borneol using “Non-Green” chemistry principles.

Answer 1

The 12 principles of Green Chemistry are:

1. Waste Prevention

2. Atom Economy

3. Less Hazardous Chemical Syntheses

4. Designing Safer Chemicals

5. Safer Solvent and Auxiliaries

6. Design for Energy Efficient

7. Use of Renewable Feedstocks

8. Reduce Derivatives

9. Catalysis

10. Design for Degradation

11. Real time analysis for Pollution Prevention

12. Inherently safer chemistry for accident Prevention.

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