The reaction between an alkene and HBr is an electrophilic addition reaction
R- CH = CH2 + H-Br R-CH(Br)-CH3
Here the number of moles of product is less than that of reactants (ng = 1 - 2 = -1)
We know entropy is the measure of randomness or disorderdness. A reaction is favoured when there is an increase in entropy. Here number of moles are decreasing and hence the reaction is entropically disfavoured
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