Question

How does the temperature and specific heat capacity of a sample of water (the calorimeter) change...

  1. How does the temperature and specific heat capacity of a sample of water (the calorimeter) change as a different mass or temperature of hot metal is added to it?
  2. How does the temperature and specific heat capacity of a sample of water (the calorimeter) change as the volume of water is changed?
  3. How does the molar enthalpy of dissolution change with the amount of substance added to water?
  4. How does the molar enthalpy of dissolution change with the volume of water the substance is added to?
  5. How does the molar enthalpy of neutralization change with the amount and/or concentration of acid and base present?

Homework Answers

Answer #1

Specific heat of a substance is the amount of heat required to increase the temperature of 1 g of the substance by 1°C. It is an intrinsic property. The total amount of heat energy absorbed or released by a substance and also the change in temperature may vary with the mass but the specific heat does not change.
Similarly change in volume changes the density of the substance but the specific heat is not affected.

Total enthalpy change during a process is an extensive property and changes with mass or volume of a substance.
However, molar enthalpy change for a process(here dissolution) is an intensive property and does not change with the quantity of the substance.

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