Calculate the vapor pressure for water when adding 10g of glucose to 1L of water at 20 degrees celcius. (The vapor pressure of water at this temperature is 17.5 torr)
Calculate the vapor pressure for water when adding 10g of glucose to 1L of water at 20 degrees celcius. (The vapor pressure of water at this temperature is 17.5 torr)
Solution:- density of water = 1 g/ml
thus, mass of 1 litres of water = 1000 g
molar mass of water = 18 g/mole
thus, moles of 1000 g of water = 1000/18 = 55.56 mole
Now, molar mass of glucose = 180 g/mole
thus, moles of 10 g of glucose = 10/180 = 0.0556 moles
Mole fraction of glucose = moles of glucose/(moles of glucose + moles of water) = 0.0556/(55.56+0.0556) = 0.001
Now, As per Raoult's Law, fractional change in vapour pressure = mole fraction of solute
Let the vapour pressure of the glucose-water solution be P
Thus, (17.5-P)/17.5 = 0.001
or, P = 17.4825 torr
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