Calculate ΔGrxn at 35 ∘C. for the following reactions: 2CH4(g)→C2H6(g)+H2(g) 2NH3(g)→N2H4(g)+H2(g) N2(g)+O2(g)→2NO(g) 2KClO3(s)→2KCl(s)+3O2(g)
ΔGrxn = ΔGform products - ΔGform reactants
= -32.1 - (2 * 68.4) KJ/mol
= -168.9 KJ/mol
part b
ΔGrxn= ΔGform products - ΔGform reactants
ΔGrxn= 120.3 - (-2* 16.4) = 153.1 KJ/mol
ΔGform H2= 0 because H2 is standard state of Hydrogen.
part c
ΔGrxn = 2 * ΔGformNO
because nitrogen and oxygen are in their standard states
= 2*86.6 KJ/mol = 137.2 KJ/mol
part d
ΔGrxn = [2ΔGf(KCl (s)) + 3ΔGf(O2 (g))] - [2ΔGf(KClO3 (s))]
[2(-408.32) + 3(0)] - [2(-289.91)] = -236.82 kJ
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