Question

Which of the following would result in a slower reaction? a larger value of ?G‡ for...

Which of the following would result in a slower reaction?

a larger value of ?G for the reaction
a greater number of collisions between reacting molecules in a given period of time
a larger fraction of collisions that occur with the proper orientation for reaction
a more stable transition state

Homework Answers

Answer #1
a larger value of ΔG for the reaction: It will result in slower rate as more the negative value of free energy change more the spontaneity of reaction
a greater number of collisions between reacting molecules in a given period of time: More the collision more the rate of reaction
a larger fraction of collisions that occur with the proper orientation for reaction: More the effective collision more the rate of reaction
a more stable transition state: More the stability of transition state more the rate of reaction

So answer is a larger value of ΔG for the reaction

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