Question

For the reaction :             2ClO2(g) + 2OH-(g) à ClO3-(g) + ClO2-(aq) + H2O(l) was studied...

For the reaction :

            2ClO2(g) + 2OH-(g) à ClO3-(g) + ClO2-(aq) + H2O(l) was studied at 25oC and the following results were obtained.

[ClO2]o M

[OH-]o M

Initial rate, M/s

0.0500

0.100

5.75 x 10-2

0.100

0.100

2.30 x 10-1

0.100

0.0500

1.15 x 10-1

a) Calculate the order of reaction with respect to ClO2 and OH-

b) Calculate the rate constant for the reaction

c) Write the rate law of the reaction.

Homework Answers

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
The reaction 2 ClO2(aq) + 2 OH-(aq) ClO3-(aq) + ClO3-(aq) + H2O(l) was studied at a...
The reaction 2 ClO2(aq) + 2 OH-(aq) ClO3-(aq) + ClO3-(aq) + H2O(l) was studied at a certain temperature with the following results: Experiment [ClO2(aq)] (M) [OH-(aq)] (M) Rate (M/s) 1 0.0494 0.0494 0.0450 2 0.0494 0.0988 0.0899 3 0.0988 0.0494 0.180 4 0.0988 0.0988 0.360 (a) What is the rate law for this reaction? Rate = k [ClO2(aq)] [OH-(aq)] Rate = k [ClO2(aq)]2 [OH-(aq)] Rate = k [ClO2(aq)] [OH-(aq)]2 Rate = k [ClO2(aq)]2 [OH-(aq)]2 Rate = k [ClO2(aq)] [OH-(aq)]3 Rate...
Please explain rules as well/ Calculations, and thank you for your patience 2. 2ClO2(aq)+2OH-(aq)-ClO3-(aq)+ClO2-(aq)+H2O(I) Experiment number=...
Please explain rules as well/ Calculations, and thank you for your patience 2. 2ClO2(aq)+2OH-(aq)-ClO3-(aq)+ClO2-(aq)+H2O(I) Experiment number= 1,2 ,3 [ClO2](M) = 0.060,0.020,0.020 [OH-](M) =0.020,0.030,0.00276 Initial Rate(M/s)=0.0248,0.00276,0.00828 (A) What is the order of the overall reaction? (B) What is the order of the reaction with respect to ClO2?
1a. If 315 mL of 1x10^-4M Ca(NO3)2 is mixed with 315 mL of 1 x10^-4M NaF,...
1a. If 315 mL of 1x10^-4M Ca(NO3)2 is mixed with 315 mL of 1 x10^-4M NaF, what will occur? For CaF2, Ksp=3.4x10^-11 (I know no precipitate forms but how do you do it) 2a. 2ClO2(aq)+2OH-(aq)-ClO3-(aq)+ClO2-(aq)+H2O(I) Experiment number= 1,2 ,3 [ClO2](M) = 0.060,0.020,0.020 [OH-](M) =0.020,0.030,0.00276 Initial Rate(M/s)=0.0248,0.00276,0.00828 (A) What is the order of the overall reaction? (B) What is the order of the reaction with respect to ClO2?
The mechanism for the reaction 2 H2O2(aq) à 2 H2O(l) + O2(g) in the presence of...
The mechanism for the reaction 2 H2O2(aq) à 2 H2O(l) + O2(g) in the presence of I–(aq) is proposed to be: Step 1: H2O2(aq) + I–(aq) à H2O(l) + OI–(aq)                                   (slow) Step 2: H2O2(aq) + OI–(aq) à H2O(l) + O2(g) + I–(aq)                       (fast) What is the rate law for the overall reaction?             a. Rate = k[H2O2]2             b. Rate = k[H2O2][I–]             c. Rate = k[H2O2]2[I–]/[H2O]             d. Rate = k[H2O2][OI–]             e. Rate = k[H2O2]
Consider an electrochemical cell based on the following reaction: Zn(s) + 2H2O(l) + 2OH-(aq) ⇄ [Zn(OH)4]2-(aq)...
Consider an electrochemical cell based on the following reaction: Zn(s) + 2H2O(l) + 2OH-(aq) ⇄ [Zn(OH)4]2-(aq) + H2(g) All dissolved species are at 2.5 x 10-3 M; pressure of H2 is 1 bar (standard state) Use the Nernst equation to calculate E.
Calculate ΔG for the reaction H2O (l) <=>H+ (aq) + OH- (aq) at 25C for the...
Calculate ΔG for the reaction H2O (l) <=>H+ (aq) + OH- (aq) at 25C for the following conditions in (kJ/mol)? (a) [H+] = 1.0 x10-3 M, [OH-] = 1.0 x 10-4 M (b) [H+] = 3.3 M, [OH-] = 4.8 x 10-4 M
The chemical reaction: 4 NH3(g) + 5 O2(g) à 4 NO (g) + 6 H2O (g)...
The chemical reaction: 4 NH3(g) + 5 O2(g) à 4 NO (g) + 6 H2O (g) is observed to have a reaction rate of 0.100 mol / (L×s). What is the rate of change for NH3 in this reaction in mol / (L×s)? The answer is -.400 PLEASE EXPLAIN YOUR WORK! Thank you!
The rate law for the reaction H+(aq) + OH−(aq) ---> H2O(l) is Rate = k[H+ ][OH−...
The rate law for the reaction H+(aq) + OH−(aq) ---> H2O(l) is Rate = k[H+ ][OH− ], with
 k = 1.3 x 10^11 mol-1 L s-1 at 25 deg C. In an experiment, 0.500 L of 0.020 mol L-1 KOH(aq) is rapidly mixed with an equal volume of 0.020 mol L-1 HBr(aq). Calculate the time, in seconds, required for [H+ ] to decrease to 1.0x 10^-7 mol L-1.

The kinetics of the following second-order reaction were studied as a function of temperature: C2H5Br(aq)+OH−(aq)→C2H5OH(l)+Br−(aq) Temperature...
The kinetics of the following second-order reaction were studied as a function of temperature: C2H5Br(aq)+OH−(aq)→C2H5OH(l)+Br−(aq) Temperature (∘C) k (L/mol⋅s) 25 8.81×10−5 35 0.000285 45 0.000854 55 0.00239 65 0.00633 Determine the activation energy for the reaction. Determine the frequency factor for the reaction. Determine the rate constant at 10 ∘C. If a reaction mixture is 0.155 M in C2H5Br, and 0.260 M in OH−, what is the initial rate of the reaction at 90 ∘C?
Calculate the following for the reaction; O2(g) + 4H+(aq) + 4Fe2+(aq) -> 2H2O(l) + 4 Fe3+(aq)...
Calculate the following for the reaction; O2(g) + 4H+(aq) + 4Fe2+(aq) -> 2H2O(l) + 4 Fe3+(aq) (a) ΔGo at 25oC (b) ΔG at 25oC when [Fe2+] = [Fe3+] = 0.200 M, Po2 = 0.800 atm, and the pH = 2.56