What is the limiting reagent for meso-hydrobenzoin? (Benzil + NaBH4 ------> meso-hydrobenzoin)
Benzoin= 1.01g MW= 212.24 g/mol
Sodium Borohydride= .11g MW= 46.07g/mol
Recrystalized meso-hydrobenzoin= .91 g MW= 214.26g/mol
(When in class my teacher said something about there being 4 hydrogens on Sodium Borohydride but only one attacks the carbon so you will either have to divide or multiply by four? I'm not really sure what he meant by this)
The balanced reaction is
Benzil + 2H- ---> Meso -Hydrobenzoin
Here 1 NaBH4 gives 4H- , hence 2H- is given by ( 2/4) NaBH4 ie 1/2 NaBH4
Hence balanced eq becomes
Benzil + 1/2 NaBH4 ---> Meso-hydrobenzoin
Benzoin moles = mass/ Molar mass of benzoin
= 1.01 / 212.24
= 0.00476
NaBH4 moles = 0.11 /46.07 = 0.002388
As per reaction Benzoin moles = 2 times NaBH4 moles
Hence for 0.002388 moles NaBH4 we need benzoin moles = 2 x 0.002388 = 0.004776
but we had only 0.00476 moles .
Hence benzoin is relatively less , hence it is Limiting reagent
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