What is the molarity of sodium vanadate (Na3VO4) solutions if 34.6 ml of the solution are needed to titrate a .514g sample of pure potassium sulfite? VO4^-3 + SO3^-2 + 4H^+ = VO^+ +SO4^-2 + 2H2O
VO4^-3 + SO3^-2 + 4H^+---------->VO^+ +SO4^-2 + 2H2O
no of moles of K2So3 = W/G.M.Wt
= 0.514/158 = 0.00325 moles
from balanced equation
1 moles of K2So3 react with 1 moles Na3Vo4
0.00325 moles of K2So3 react with 0.00325 moles Na3VO4
molarity Na3VO4 = no of moles/volume in L
= 0.00325/0.0346 = 0.094 M
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