For which of the following titrations will the pH at the equivalence point be greater than 7?
HF with KOH |
NH3 with HBr |
HCl with Ca(OH)2 |
NaF with HCl |
answer : HF with KOH
explanation:
1) HF + KOH ------------------> KF + H2O
here KF salt is formed it is the salt of strong base and weak acid . so the pH >7
2) NH3 + HBr --------------------> NH4Br
here the salt NH4Br is the weak base and strong acid. so the pH <7
3) 2HCl + Ca(OH)2 --------------------> CaCl2 + 2H2O
it is strong acid and strong base reaction. so the pH is exactly 7
4) NaF + HCl ----------------> NaCl + HF
NaCl is neutral salt and HF is weak acid. so the pH may be 7 or less than 7 .
so ultimate answer is first option
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