An open flask sitting in a lab fridge looks empty, but we know that actually it is filled with a mixture of gases called air. If the flask volume is 1.50 L, and the air is at standard temperature and pressure, how many gaseous molecules does the flask contain?
STP conditions,
P = 1 bar = 0.987 atm
T = 273.15 k
from ideal gas equation
PV = nRT
n = PV/RT
v = 1.5 L
R = 0.0821 l.atm.k-1.mol-1
n = no of mol of air in the flask = ?
n = 0.987*1.5/(0.0821*273.15)
= 0.066 mol
at STP , 1 mol of any gas contains N0 = 6.023*10^23 molecules
No of air molecules present in flask (N) = n*N0
= 0.066*6.023*10^23
= 3.975*10^22 molecules
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