We know that Molar Mass of NaOH = 40.0 g/mol
Thus, one mol of NaOH has a mass of 40.0 g
Thus, in 20 grams of NaOH, no. of Moles = Mass / Molar Mass = (20 g) / (40.0 g/mol) = 0.50 mol
One mole of NaOH reacts with one mole of HCl to produce 1000 calories.
Thus, heat of reaction will be 1000 cal/mol
Thus, if there are only 0.50 mol of NaOH then only half the energy will be produced.
Thus, energy produced = 1000 cal/mol * 0.50 mol = 500 cal
So, 20 gram of NaOH will produce 500 calories
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