Question

rank HF, HCl and HI in order of decreasing pka and explain your reasoning.

rank HF, HCl and HI in order of decreasing pka and explain your reasoning.

Homework Answers

Answer #1

pKa values order :   HI < HCl < HF

explanation:

pKa value increases acidity decreases. lesser pKa value indicate strong acid

F, Cl , I are same group elements . the acidity order of hydrides increases it is due to increase in size of halogen atom .

if halogen atom size increases the bond length between halogen and hydrogen increases so that the bond dissociation energy is decreases . so HI bond wil be broken easily than HF bond. that means HI can readily loose H+ ion . so it is strong acid .

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