rank HF, HCl and HI in order of decreasing pka and explain your reasoning.
pKa values order : HI < HCl < HF
explanation:
pKa value increases acidity decreases. lesser pKa value indicate strong acid
F, Cl , I are same group elements . the acidity order of hydrides increases it is due to increase in size of halogen atom .
if halogen atom size increases the bond length between halogen and hydrogen increases so that the bond dissociation energy is decreases . so HI bond wil be broken easily than HF bond. that means HI can readily loose H+ ion . so it is strong acid .
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