Oxygen contains two unpaired electrons one is reduced to superoxide and the other to hydrogen peroxide in cells. Aerobic organisms produce catalase and superoxide dismutase to counteract these products , whereas these obligate anaerobs either don't produce them or produce them in very less amount . Which leaves them toxic to oxygen .
Microorganisms can be classified into groups according to their oxygen consumption;
1. Obligate aerobes : requires oxygen to survive.
2. Microaerophilic : requires low oxygen .
3. Facultative anaerobes : respires aerobically until oxygen is depleted and then comes to fermentation anaerobically .
4. Obligate anaerobes : lacks superoxide dismutase and catalase , is toxic to oxygen .
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